1/30/2010
Model Test Study on the Improved Filling Embankment in Permafrost Regions_Latest Science Articles
Resource form:Model Test Study on the Improved Filling Embankment in Permafrost Regions_Latest Science Articles
1/29/2010
The Effect of Excessive Phosphate Fertilizer on Mineral Nutrient Uptake of Chinese Cabbage Species
Effects of Biogas Residue on the Nature of Substrate and Growth of Tomato in Greenhouse
Energy Security and Contemporary International Relations_Latest Science Articles
Energy Security and Contemporary International Relations_Latest Science Articles
1/28/2010
Research on development strategy of forestry in Shanxi Province_Latest Science Articles
Research on development strategy of forestry in Shanxi Province_Latest Science Articles
1/27/2010
Controllable Soft Template for the Synthesis of Gold Nanoparticles_Latest Science Articles
Controllable Soft Template for the Synthesis of Gold Nanoparticles_Latest Science Articles
1/26/2010
The Research and Application of Digital Signature_Latest Science Articles
The Research and Application of Digital Signature_Latest Science Articles
1/18/2010
Study on BTDA-ODA Polyimide Nanofiber Prepared by Electrospinning
Electrospinning, a unique characteristic of easy operation, is one of best methods to make nanofibers. Electrospun membranes are able to form a large surface-to-volume ratio, highly porous mesh, highly length-diameter ratio and uniform fiber improves performance for many potential applications. For example, fabrics are suited to sorbing material and filtering material, because of their super adsorption, excellence filter capacity and good heat preservation, fabrics also be developed to fibers which have many functions such as antisepsis, radiation resistance, flame retardance and shielding. Aromatic polyimides, as a high performance functional fibers material, have marked excellent physical and chemical properties like thermal stability, dielectric property, radio resistant property, fire resistance, high strength, high modulus and nonpoisonous. The polyimide(PI) nanofiber was prepared by electrospinning the PAA solution, followed by thermal imidization and carbonisation. Imidized webs generated crosslinking and aromatic heterocyclic structures and carbonized with yields from 50% to 70%. The PI nanofiber has enormous potential value and will be a very promising precursor of carbon nanofiber.In this paper, different solid contents of BTDA-ODA Polyamic acid (PAA) solution were prepared with different solvent as DMF, DMAc and NMP. The non-woven membranes of polyimide for insulation are prepared by electrospinning the polyamic acid solution, followed by thermal imidization, carbonisation. Imidized webs were carbonized in the temperature range from 600℃to 1000℃under a nitrogen atmosphere. The images of fibers were characterized by scanning electron microscopy and transmission electron microscopy, heat-resistant quality of fibers was characterized by Thermogravimetric Analysis (TG) and phase structures were characterized by wide angle X-ray Diffraction (WAXD). The results showed that average diameter of PI nanofibers with DMF system (voltage was 15kV, receptor distance was 20cm and solid contents of solution was 25%)was the thinest from 150 to 250nm, diameter of PI nanofibers after heat treatment was from 300 to 500nm, bending, twisting and adhesion phenomenon were most serious within the fibers after imidization. however, PI non-woven membrane which prepared by PAA electrospun solution synthesized with NMP indicated a relatively high thermal stability, electrospining went again stcrystal structure of PI nanofiber, and it was little changed after heat treatment.
Development of Polyimide-based Carbon Nano-fiber Membrane
Polyimide(PI), as a kind of high-performance engineering material, possesses excellent physical and chemical properties. It has been widely used in microelectronics packaging, high temperature adhesive and composite, etc. High voltage electrospinning technology having advantages of simple technology and convenient operation.The diameters of fiber with continuitie ranged from several decade nanometer to hundreds nanometers. Polyimide-based carbonnano-fiber was prepared by high voltage electrospinning technology is of great potential value in application.This article based on structure and properties of polyimide, using pyromellitic dianhydride(PMDA) and bis(4-aminophenyl)ether(ODA) as monomer to prepare polyamide acid in N,N′-dimethylacetamide, and utilize high voltage electrospinning technology to prepare polyamic acid nano-fiber membrane which was further imidized into polyimidenano-fiber membrane, then use polyimidenano-fiber membrane as precursor to prepare polyimide-based carbonnano-fiber membrane through high-temperature carbonization process. Fiber diameter and non-woven pore size distribution were controlled by eletrospinning technological conditions. Scanning electronmicroscopy(SEM) and transmission electron microscopy (TEM) were utilized to investigate the surface morphology characteristics, Thermogravimetric analysis(TG), X-ray Diffraction (XRD) and infrared analysis(IR) were used to analysis and forecast structure.The results showed that polyimide-based carbonnano-fiber membrane possesses excellent thermal stability. SEM analysis shows that with the carbonation temperature increased, fiber diameter decreases gradually, distribution change narrowlly, mainly located between 100~200nm; when carbonization temperature reached 1000℃, Filamentous carbon content in polyimide-based carbon nano-fiber membrane is 96.16%. Fiber film start deoxy when temperature reached 600℃, and the structure of a graphite like formed temperature reached 700℃, after 700℃the combination of the heterocyclic may be produced to remove sulfur nitrogen oxide, then form continuous aromatic heterocyclic compounds, with temperature continue increased to 900℃fused ring aromatization happen, hexagonal carbon layer with graphite-like structure gradually increased.
1/06/2010
The Uniform Local Asymptyotics of the Overshoot of a Random Walk with Heavy-Tailed Increments
It is well known that much attention has been paid to issues of the uniform local asymptotics of the overshoot of a random walk with heavy-tailed increments. Asmussen et al. (2003) has got a special result of local asymptotics of the overshoot of a random walk which has some conditions of moment. Rencently, Tang (2007) has investigated the non-local asymptotics of the overshoot of a random walk. In the first chapter of this paper, we introduce some fundmential knowledge about our paper. Furthermore, we fall back a lot of results which have been got before and give the aim of our paper. In the second chapter, we obtain the uniform local asymptotics of the overshoot of a random walk with heavy-tailed increments. When the overshoot is in (x + y, x + y + T) for some 0<T<∞, we discuss the asymptotics for two cases about y, respectively. Firstly, y≥f(x) for any positive function f(x)→∞as x→∞; secondly, y∈[0, N] for any 0<N<∞. Based on above results, we discuss them further and get a result of the uniform local asymptotics of the overshoot of a random walk for the case y≥0. The obtained results require certain uniform requirements for y. At last of this paper, we give a corollary and some remarks. We illustrate that the two results of the second chapter are meaningful by the corollary, and these remarks show the direction of our further research.
Merit Function Method for Structured Monotone Variational Inequalities
This paper presents a merit function method for structured monotone variational inequalities.Numerical results illustrates the efficiency of this method.1.Since 1960s,the theory and algorithms for finite-dimensional variational inequalities developed rapidly.Variational inequalities and complementarity problems have been developed an important field in applied mathematics.They have been widely used not only in nonlinear programming but in differential equation,mechanics,cybernetics,game theory,economic equilibrium theory,social and economic model,etc.Therefore,variational inequality and its application have become a focus in mathematics.2.In Chapter 3,we constructed a merit function based the model for structured monotone variational inequalities.We transformed the original problem to an optimization problem which possesses a very simple structure for calculation in our method.At last,we gave the global convergence condition.3.In Chapter 4,we introduced some algorithms for variational problems.Some numerical examples with ball constraints or box constraints were given.Numerical results verified the validity of the method provided in chapter three.